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Graphene Nanoribbons by Chemists: Nanometer‐Sized, Soluble, and Defect‐Free

2011; Wiley; Volume: 50; Issue: 11 Linguagem: Inglês

10.1002/anie.201006593

1521-3773

Lukas Dössel, Lileta Gherghel, Xinliang Feng, Kläus Müllen,

Molecular Junctions and Nanostructures

Closing the zipper: A method for the bottom-up organic synthesis of defect-free graphene nanoribbons in solution has been developed. Polyphenylene precursors with a unique kinked backbone enabled full cyclodehydrogenation in a single reaction step by an intramolecular Scholl reaction with FeCl3 (see scheme). Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.