Artigo Acesso aberto Revisado por pares

Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex

2011; Wiley; Volume: 50; Issue: 25 Linguagem: Inglês

10.1002/anie.201100907

ISSN

1521-3773

Autores

Isaac Garcia‐Bosch, Anna Company, Clyde W. Cady, Stenbjörn Styring, Wesley R. Browne, Xavi Ribas, Miguel Costas,

Tópico(s)

Metalloenzymes and iron-sulfur proteins

Resumo

HAT trick: [MnIV(OH)2(H,MePytacn)]2+ (A) and [MnIV(O)(OH)(H,MePytacn)]+ (B) differ in their reactions with CH bonds: compound A engages in typical single-step hydrogen atom transfer (HAT) reactions, whereas B first forms a substrate–B encounter complex (C; see scheme). This equilibrium alters the relative CH reactivity from that expected from CH bond dissociation energies. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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