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BIBTEX RIS

Dimeric iron n-confused porphyrin complexesElectonic supplementary information (ESI) available: general information; preparation and crystal data for 6 and 7; Fig. S1: absorption spectra for 6 and 7; Figs. S2 and S3: magnetic susceptibility data for 6 and 7. See http://www.rsc.org/suppdata/cc/b2/b202679a/

2002; Royal Society of Chemistry; Issue: 14 Linguagem: Inglês

10.1039/b202679a

ISSN

1364-548X

Autores

Chen‐Hsiung Hung, Wan‐Chin Chen, Gene‐Hsiang Lee, Shie‐Ming Peng,

Tópico(s)

Magnetism in coordination complexes

Resumo

A dimeric iron N-confused porphyrin, [Fe(NCTPP)]2 was obtained from the anaerobic reaction of Fe(NCTPP)Br with NaSePh while under aerobic conditions a hydroxo bridged iron dimer with Na bridging the outer-N atoms was obtained and oxygenation occurred on the inner core pyrrolic carbon to form a novel ONCTPP porphyrinic ring.

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