Portal de Periódicos da CAPES

Crystal Engineering of an nbo Topology Metal–Organic Framework for Chemical Fixation of CO 2 under Ambient Conditions

2014; Wiley; Volume: 53; Issue: 10 Linguagem: Inglês

10.1002/anie.201309778

1521-3773

Wen‐Yang Gao, Yao Chen, Youhong Niu, Kia Williams, Lindsay Cash, P.J. Perez, Łukasz Wojtas, Jianfeng Cai, Yu‐Sheng Chen, Shengqian Ma,

Covalent Organic Framework Applications

Crystal engineering of the nbo metal-organic framework (MOF) platform MOF-505 with a custom-designed azamacrocycle ligand (1,4,7,10-tetrazazcyclododecane-N,N',N'',N'''-tetra-p-methylbenzoic acid) leads to a high density of well-oriented Lewis active sites within the cuboctahedral cage in MMCF-2, [Cu2(Cu-tactmb)(H2O)3(NO3)2]. This MOF demonstrates high catalytic activity for the chemical fixation of CO2 into cyclic carbonates at room temperature under 1 atm pressure.