The anionic thia-Fries rearrangement of aryl triflates
2003; Royal Society of Chemistry; Issue: 3 Linguagem: Inglês
10.1039/b210648e
ISSN1364-548X
AutoresJ.P.H. Charmant, Alan M. Dyke, Guy C. Lloyd‐Jones,
Tópico(s)Fluorine in Organic Chemistry
ResumoAryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.
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