Artigo Revisado por pares

The anionic thia-Fries rearrangement of aryl triflates

2003; Royal Society of Chemistry; Issue: 3 Linguagem: Inglês

10.1039/b210648e

ISSN

1364-548X

Autores

J.P.H. Charmant, Alan M. Dyke, Guy C. Lloyd‐Jones,

Tópico(s)

Fluorine in Organic Chemistry

Resumo

Aryl triflates undergo LDA-mediated rearrangement to generate o-hydroxyaryl trifluoromethylsulfones. In some cases, partitioning between rearrangement and aryne generation can be controlled.

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