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Catalytic and Direct Oxyphosphorylation of Alkenes with Dioxygen and H‐Phosphonates Leading to β‐Ketophosphonates

2011; Wiley; Volume: 50; Issue: 39 Linguagem: Inglês

10.1002/anie.201100219

1521-3773

Wei Wei, Jian‐Xin Ji,

Asymmetric Hydrogenation and Catalysis

Direct access: The title reaction has been developed under mild reaction conditions (see scheme; DMSO=dimethyl sulfoxide). This reaction can be effectively scaled up and offers not only a green and attractive approach to β-ketophosphonates, but also a useful example of direct incorporation of an oxygen atom from dioxygen into organic frameworks.