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Application of a chiral metal–organic framework in enantioselective separation

2011; Royal Society of Chemistry; Volume: 47; Issue: 44 Linguagem: Inglês

10.1039/c1cc14893a

1364-548X

Mohan Padmanaban, Philipp Müller, Christian Lieder, Kristina Gedrich, Ronny Grünker, Volodymyr Bon, Irena Senkovska, Sandra Baumgärtner, Sabine Opelt, Silvia Paasch, Eike Brunner, Frank Glorius, Elias Klemm, Stefan Kaskel,

Polyoxometalates: Synthesis and Applications

A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal–organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.