A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2 Bridges: Synthesis, Crystal Structure, and Properties

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A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2 Bridges: Synthesis, Crystal Structure, and Properties

2009; Wiley; Volume: 48; Issue: 21 Linguagem: Inglês

10.1002/anie.200900509

ISSN

1521-3773

Autores

Bao‐Hua Zhu, Yusuke Shibata, Satoshi Muratsugu, Yoshinori Yamanoi, Hiroshi Nishihara,

Tópico(s)

Perovskite Materials and Applications

Resumo

Two dragons playing ball: Direct metal-metal bond formation using a pi-conjugated dinuclear metalladithiolene complex with two electron-deficient metal centers as building blocks led to a cyclic double trinuclear heterometalladithiolene cluster with two parallel plane bridges (see structure; Rh pink, Mo green, S yellow, C gray, O red).

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A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2 Bridges: Synthesis, Crystal Structure, and Properties