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Energetic Nitrogen‐Rich Derivatives of 1,5‐Diaminotetrazole

2008; Wiley; Volume: 47; Issue: 33 Linguagem: Inglês

10.1002/anie.200801886

1521-3773

Young Hoon Joo, Brendan Twamley, Sonali Garg, Jean’ne M. Shreeve,

Chemical Reactions and Mechanisms

High-energy-density materials can be obtained by reaction of monosubstituted hydrazines with cyanogen azide to generate 1,5-diaminotetrazole derivatives. Azidohydrazones are postulated as intermediates in this reaction (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z801886_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.