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Photoinduced Gold(I)–Gold(I) Chemical Bonding in Dicyanoaurate Oligomers

2013; Wiley; Volume: 52; Issue: 39 Linguagem: Inglês

10.1002/anie.201305487

1521-3773

Ganglong Cui, Xiaoyan Cao, Wei‐Hai Fang, Michael Dolg, Walter Thiel,

Nanocluster Synthesis and Applications

Angewandte Chemie International EditionVolume 52, Issue 39 p. 10281-10285 Communication Photoinduced Gold(I)–Gold(I) Chemical Bonding in Dicyanoaurate Oligomers† Dr. Ganglong Cui, Dr. Ganglong Cui Chemistry College, Beijing Normal University, Beijing 100875 (China) Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. Xiao-Yan Cao, Dr. Xiao-Yan Cao Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany)Search for more papers by this authorProf. Dr. Wei-Hai Fang, Corresponding Author Prof. Dr. Wei-Hai Fang fangwh@bnu.edu.cn Chemistry College, Beijing Normal University, Beijing 100875 (China) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorProf. Dr. Michael Dolg, Corresponding Author Prof. Dr. Michael Dolg m.dolg@uni-koeln.de Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorProf. Dr. Walter Thiel, Corresponding Author Prof. Dr. Walter Thiel thiel@kofo.mpg.de Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this author Dr. Ganglong Cui, Dr. Ganglong Cui Chemistry College, Beijing Normal University, Beijing 100875 (China) Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorDr. Xiao-Yan Cao, Dr. Xiao-Yan Cao Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany)Search for more papers by this authorProf. Dr. Wei-Hai Fang, Corresponding Author Prof. Dr. Wei-Hai Fang fangwh@bnu.edu.cn Chemistry College, Beijing Normal University, Beijing 100875 (China) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorProf. Dr. Michael Dolg, Corresponding Author Prof. Dr. Michael Dolg m.dolg@uni-koeln.de Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this authorProf. Dr. Walter Thiel, Corresponding Author Prof. Dr. Walter Thiel thiel@kofo.mpg.de Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany) Wei-Hai Fang, Chemistry College, Beijing Normal University, Beijing 100875 (China) Michael Dolg, Institut für Theoretische Chemie, Universität zu Köln, Greinstr. 4, 50939 Köln (Germany) Walter Thiel, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr (Germany)Search for more papers by this author First published: 12 August 2013 https://doi.org/10.1002/anie.201305487Citations: 36 † W.F. thanks the Major State Basic Research Development Programs (grant number 2011CB808503) and the NSFC (grant number 21033002). G.C. thanks the Alexander-von-Humboldt foundation. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Not only σ*σ but also σ*π: High-level electronic structure calculations reveal the σ*σ and σ*π bonding patterns for AuI–AuI bonding in excited states and suggest two conformation-dependent photophysical relaxation mechanisms for dicyanoaurate oligomers (n=2–5; see picture) in aqueous solution. These insights into the excited-state electronic structure should also be relevant for other gold complexes with a similar gold scaffold. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description anie_201305487_sm_miscellaneous_information.pdf1.1 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume52, Issue39September 23, 2013Pages 10281-10285 RelatedInformation