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BIBTEX RIS

A novel chiral terpyridine macrocycle as a fluorescent sensor for enantioselective recognition of amino acid derivativesElectronic supplementary information (ESI) available: plots for estimation of binding constants for tpy macrocycle 1 with (R)-PhEtOMe. See http://www.rsc.org/suppdata/cc/b3/b313960c/

2004; Royal Society of Chemistry; Issue: 4 Linguagem: Inglês

10.1039/b313960c

ISSN

1364-548X

Autores

Wing‐Leung Wong, Ka‐Hung Huang, Pang‐Fei Teng, Chi‐Sing Lee, Hoi‐Lun Kwong,

Tópico(s)

Porphyrin and Phthalocyanine Chemistry

Resumo

Terpyridine macrocycle 1 is shown to be a strong chelating agent for organic ammonium salts and also a useful chromophore in fluorescent sensing. It exhibits very good enantioselectivity (Kobs (S)/Kobs (R) = 3.8) in chiral discrimination of α-phenylglycine methyl ester hydrochloride (PhEtOMe).

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