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Artigo Revisado por pares
BIBTEX RIS

Nucleophilic Perfluoroalkylation of Aldehydes, Ketones, Imines, Disulfides, and Diselenides

2006; American Chemical Society; Volume: 71; Issue: 9 Linguagem: Inglês

10.1021/jo060250j

ISSN

1520-6904

Autores

Chaya Pooput, William R. Dolbier, Maurice Médebielle,

Tópico(s)

Inorganic Fluorides and Related Compounds

Resumo

Using a procedure analogous to that developed for nucleophilic trifluoromethylation, the perfluoroalkyl anion reagents created by mixing C2F5I and n-C4F9I with tetrakis(dimethylamino)ethylene (TDAE) were effective in their nucleophilic reactions with aldehydes, ketones, imines, disulfides, and diselenides. Irradiation proved beneficial in the aldehyde and ketone reactions.

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