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A Luminescent Metal–Organic Framework as a Turn‐On Sensor for DMF Vapor

2012; Wiley; Volume: 52; Issue: 2 Linguagem: Inglês

10.1002/anie.201207610

1521-3773

Li Yu, Shanshan Zhang, Datong Song,

Molecular Sensors and Ion Detection

A real turn-on: a luminescent lanthanide metal-organic framework shows strong and fast turn-on responses to N,N-dimethylformamide (DMF) vapor. The selective turn-on effect is triggered mainly by DMF-ligand interactions, along with the removal of quencher, water, from the metal coordination sphere.