A Convenient New Route to Tetradentate and Pentadentate Macrocyclic Tetraamide Ligands
1999; American Chemical Society; Volume: 1; Issue: 8 Linguagem: Inglês
10.1021/ol990155f
ISSN1523-7060
AutoresLeonard C. Rorrer, Stephen D. Hopkins, Michele K. Connors, Daniel W. Lee, Matthew V. Smith, Hilary Rhodes, Erich S. Uffelman,
Tópico(s)Click Chemistry and Applications
ResumoA crucial diamide diamine intermediate in the synthesis of tetradentate macrocyclic tetraamide ligands protected against oxidative decomposition has been synthesized without the use of potentially hazardous organic azide intermediates. This intermediate has also been used to synthesize a new class of pentadentate macrocyclic tetraamide ligands.
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