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A Broad Substrate‐Scope Method for Fast, Efficient and Selective Hydrogen Peroxide‐Epoxidation

2009; Wiley; Volume: 351; Issue: 3 Linguagem: Inglês

10.1002/adsc.200800650

1615-4169

Isaac Garcia‐Bosch, Xavi Ribas, Miguel Costas,

Porphyrin and Phthalocyanine Chemistry

Abstract magnified image The efficient epoxidation of a broad range of olefins using hydrogen peroxide (H 2 O 2 ) as the oxidant has been accomplished by a manganese catalyst that exhibits an uncommon chemoselectivity.