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BIBTEX RIS

Total Syntheses of Secalonic Acids A and D

2014; Wiley; Volume: 53; Issue: 12 Linguagem: Inglês

10.1002/anie.201311260

ISSN

1521-3773

Autores

Tian Qin, John A. Porco,

Tópico(s)

Chemical synthesis and alkaloids

Resumo

Abstract Total syntheses of the dimeric tetrahydroxanthone natural products secalonic acids A and D are described. Key steps involve kinetic resolution of the tetrahydroxanthone core structure using homobenzotetramisole catalysis and late‐stage copper(I)‐mediated homodimerization of complex aryl stannane monomers.

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