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Bismuthine BiH3: Fact or Fiction? High-Resolution Infrared, Millimeter-Wave, and Ab Initio Studies

2002; Wiley; Volume: 41; Issue: 14 Linguagem: Inglês

10.1002/1521-3773(20020715)41

ISSN

1521-3773

Autores

W. Jerzembeck, H. Bürger, L. F. Constantin, L. Margulès, J. Demaison, Jürgen Breidung, Walter Thiel,

Tópico(s)

Organophosphorus compounds synthesis

Resumo

Fact! That is the answer to the question posed in the title. Over 40 years passed before the synthesis of bismuthine (BiH3; see picture) by Amberger was confirmed successfully. High-resolution IR and millimeter-wave spectroscopy as well as ab initio calculations now provide a detailed picture of the molecular structure of this compound.

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