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Completely Stereospecific Self-Assembly of a Circular Helicate

1998; Wiley; Volume: 37; Issue: 3 Linguagem: Inglês

10.1002/(sici)1521-3773(19980216)37

1521-3773

Olimpia Mamula, Alex von Zelewsky, Gérald Bernardinelli,

Porphyrin and Phthalocyanine Chemistry

Angewandte Chemie International EditionVolume 37, Issue 3 p. 289-293 Communication Completely Stereospecific Self-Assembly of a Circular Helicate Olimpia Mamula, Olimpia Mamula Institute of Inorganic Chemistry, University of Fribourg, Perolles, CH-1700 Fribourg (Switzerland), Fax: Int. code+(41) 26 300-9738Search for more papers by this authorAlex von Zelewsky, Alex von Zelewsky alexander.vonzelewsky@unifr.ch Institute of Inorganic Chemistry, University of Fribourg, Perolles, CH-1700 Fribourg (Switzerland), Fax: Int. code+(41) 26 300-9738Search for more papers by this authorGérald Bernardinelli, Gérald Bernardinelli Laboratory of X-Ray Crystallography, University of Geneva, 24, quai E. Ansermet, CH-1211 Geneva (Switzerland)Search for more papers by this author Olimpia Mamula, Olimpia Mamula Institute of Inorganic Chemistry, University of Fribourg, Perolles, CH-1700 Fribourg (Switzerland), Fax: Int. code+(41) 26 300-9738Search for more papers by this authorAlex von Zelewsky, Alex von Zelewsky alexander.vonzelewsky@unifr.ch Institute of Inorganic Chemistry, University of Fribourg, Perolles, CH-1700 Fribourg (Switzerland), Fax: Int. code+(41) 26 300-9738Search for more papers by this authorGérald Bernardinelli, Gérald Bernardinelli Laboratory of X-Ray Crystallography, University of Geneva, 24, quai E. Ansermet, CH-1211 Geneva (Switzerland)Search for more papers by this author First published: 17 December 1998 https://doi.org/10.1002/(SICI)1521-3773(19980216)37:3 3.0.CO;2-MCitations: 149AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract A nanoscale turbine wheel is an apt description of the structure of the enantiomerically pure helicate [Ag6(L2)6]6+ (1), which precipitates as PF6 salt on mixing dissolved AgPF6 with the ligand L2 (a bis-bidentate ligand comprising two condensed α-pinene/bipyridine units linked by a xylylene bridge). The helicate has an outer diameter of about 3 nm and an inner diameter of 0.84 nm, and is a potential model for the study of stereospecific recognition processes. Citing Literature Volume37, Issue3February 16, 1998Pages 289-293 RelatedInformation