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Cationic Ru II Complexes with N‐Heterocyclic Carbene Ligands for UV‐Induced Ring‐Opening Metathesis Polymerization

2008; Wiley; Volume: 47; Issue: 17 Linguagem: Inglês

10.1002/anie.200705220

1521-3773

Dongren Wang, Klaus Wurst, Wolfgang Knolle, Ulrich Decker, Lutz Prager, Sergej Naumov, Michael R. Buchmeiser,

Chemical Synthesis and Analysis

Angewandte Chemie International EditionVolume 47, Issue 17 p. 3267-3270 Communication Cationic RuII Complexes with N-Heterocyclic Carbene Ligands for UV-Induced Ring-Opening Metathesis Polymerization† Dongren Wang Dr., Dongren Wang Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorKlaus Wurst Dr., Klaus Wurst Dr. Institut für Allgemeine Anorganische und Theoretische Chemie Universität Innsbruck, Innrain 52a, 6020 Innsbruck, AustriaSearch for more papers by this authorWolfgang Knolle Dr., Wolfgang Knolle Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorUlrich Decker Dr., Ulrich Decker Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorLutz Prager Dr., Lutz Prager Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorSergej Naumov Dr., Sergej Naumov Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorMichael R. Buchmeiser Prof. Dr., Michael R. Buchmeiser Prof. Dr. michael.buchmeiser@iom-leipzig.de Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfm Institut für Technische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, GermanySearch for more papers by this author Dongren Wang Dr., Dongren Wang Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorKlaus Wurst Dr., Klaus Wurst Dr. Institut für Allgemeine Anorganische und Theoretische Chemie Universität Innsbruck, Innrain 52a, 6020 Innsbruck, AustriaSearch for more papers by this authorWolfgang Knolle Dr., Wolfgang Knolle Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorUlrich Decker Dr., Ulrich Decker Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorLutz Prager Dr., Lutz Prager Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorSergej Naumov Dr., Sergej Naumov Dr. Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfmSearch for more papers by this authorMichael R. Buchmeiser Prof. Dr., Michael R. Buchmeiser Prof. Dr. michael.buchmeiser@iom-leipzig.de Leibniz-Institut für Oberflächenmodifizierung e.V. (IOM), Permoserstrasse 15, 04318 Leipzig, Germany, Fax: (+49) 341-235-2584 http://www.iom-leipzig.de/index_e.cfm Institut für Technische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, GermanySearch for more papers by this author First published: 08 April 2008 https://doi.org/10.1002/anie.200705220Citations: 85 † This work was supported by the Deutsche Forschungsgemeinschaft (DFG, project BU 2174/2-1), by the Federal Government of Germany and the Freistaat Sachsen. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Open sesame: Novel cationic RuII complexes with N-heterocyclic carbene ligands (see structure) have been prepared and used as UV-triggerable photoinitiators for ring-opening metathesis polymerization. They may be used for the high-yield synthesis of bulk polymers as well as for surface functionalization. Laser pulse radiolysis and NMR spectroscopy experiments supported by quantum chemical calculations give insight into the initiation mechanism. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z705220_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume47, Issue17April 14, 2008Pages 3267-3270 RelatedInformation