A Spin‐Admixed Ruthenium Complex
2004; Wiley; Volume: 44; Issue: 2 Linguagem: Inglês
10.1002/anie.200461463
ISSN1521-3773
AutoresM.C. Barral, Santiago Herrero, Reyes Jiménez‐Aparicio, M.R. Torres, F.A. Urbanos,
Tópico(s)Metal complexes synthesis and properties
ResumoAngewandte Chemie International EditionVolume 44, Issue 2 p. 305-307 Communication A Spin-Admixed Ruthenium Complex† M. Carmen Barral Dr., M. Carmen Barral Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorSantiago Herrero Dr., Santiago Herrero Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorReyes Jiménez-Aparicio Dr., Reyes Jiménez-Aparicio Dr. [email protected] Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorM. Rosario Torres Dr., M. Rosario Torres Dr. Centro de Asistencia a la Investigación de Rayos X, Facultad de Ciencias Químicas, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, SpainSearch for more papers by this authorFrancisco A. Urbanos Dr., Francisco A. Urbanos Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this author M. Carmen Barral Dr., M. Carmen Barral Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorSantiago Herrero Dr., Santiago Herrero Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorReyes Jiménez-Aparicio Dr., Reyes Jiménez-Aparicio Dr. [email protected] Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this authorM. Rosario Torres Dr., M. Rosario Torres Dr. Centro de Asistencia a la Investigación de Rayos X, Facultad de Ciencias Químicas, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, SpainSearch for more papers by this authorFrancisco A. Urbanos Dr., Francisco A. Urbanos Dr. Departamento de Química Inorgánica, Universidad Complutense, Ciudad Universitaria, 28040 Madrid, Spain, Fax: (+34) 91-394-4352Search for more papers by this author First published: 21 December 2004 https://doi.org/10.1002/anie.200461463Citations: 57 † We are grateful to the Ministerio de Ciencia y Tecnología (Dirección General de Investigación, project no. BQU2000-0643) for financial support. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Graphical Abstract The unusual magnetic behavior of [Ru2(μ-O2CMe)(μ-DPhF)3(H2O)]BF4⋅0.5 CH2Cl2 (1; DPhF=N,N′-diphenylformamidinate), which is intermediate between that of compounds with spin states S=1/2 and S=3/2, is attributed to a quantum mechanical spin admixture. This phenomenon results from a multiple bond between the metal atoms which permits an appropriate disposition of molecular orbitals. Citing Literature Volume44, Issue2December 27, 2004Pages 305-307 RelatedInformation
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