Chiral Phosphoric Acid Catalyzed Peroxidation of Imines
2010; Wiley; Volume: 49; Issue: 37 Linguagem: Inglês
10.1002/anie.201002972
ISSN1521-3773
AutoresWen‐Hua Zheng, Łukasz Wojtas, Jon C. Antilla,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoSomething to COO about: The title reaction provides direct access to α-amino peroxides with high enantioselectivity (see scheme). The phosphoric acid catalyst is thought to activate both the nucleophile and electrophile through hydrogen-bonding interactions. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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