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Molecular orbital analysis of the bonding in low nuclearity gold and platinum tertiary phosphine complexes and the development of isolobal analogies for the M(PR3) fragment

1982; Elsevier BV; Volume: 232; Issue: 2 Linguagem: Inglês

10.1016/s0022-328x(00)87645-7

1872-8561

David G. Evans, D. Michael P. Mingos,

Synthesis and characterization of novel inorganic/organometallic compounds

The stoichiometries and geometries of gold and platinum tertiary phosphine cluster compounds of the type Mn(PR3)nx+ (n = 3–6) have been analysed using extended Hückel molecular orbital calculations. The isolobal nature of the M(PH3) fragment depends critically on the nature of the metal atom M, and may be used to provide a basis for predicting a wide spectrum of homo- and hetero-nuclear metal cluster compounds.