Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2This work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13

Artigo Revisado por pares

Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2This work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002.

2003; Royal Society of Chemistry; Volume: 5; Issue: 2 Linguagem: Inglês

10.1039/b212313b

ISSN

1463-9270

Autores

Dave J. Adams, Weipen Chen, Eric G. Hope, Susanne Lange, Alison M. Stuart, Andrew J. West, Jianliang Xiao,

Tópico(s)

Organometallic Complex Synthesis and Catalysis

Resumo

Four chiral perfluoroalkylated monodentate phosphorus(III) ligands have been prepared and characterised. These ligands have been evaluated in the rhodium-catalysed asymmetric hydrogenation of dimethyl itaconate in both dichloromethane and supercritical CO2 (scCO2) and compared with the parent, non-perfluoroalkylated, catalyst systems.

Ver no editor

Altmetric

PlumX

Entrar

Lembrar minha senha

Receber meu e-mail de confirmação

Asymmetric hydrogenation with perfluoroalkylated monodentate phosphorus(iii) ligands in supercritical CO2 and CH2Cl2This work was presented at the Green Solvents for Catalysis Meeting held in Bruchsal, Germany, 13–16th October 2002.