Amplified Chiral Transformation through Helical Assembly
2007; Wiley; Volume: 46; Issue: 34 Linguagem: Inglês
10.1002/anie.200701668
ISSN1521-3773
AutoresKunihiko Toyofuku, Md. Akhtarul Alam, Akihiko Tsuda, Norifumi Fujita, Shigeru Sakamoto, Kentaro Yamaguchi, Takuzo Aida,
Tópico(s)Supramolecular Chemistry and Complexes
ResumoAngewandte Chemie International EditionVolume 46, Issue 34 p. 6476-6480 Communication Amplified Chiral Transformation through Helical Assembly† Kunihiko Toyofuku, Kunihiko Toyofuku Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorMd. Akhtarul Alam Dr., Md. Akhtarul Alam Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorAkihiko Tsuda Dr., Akihiko Tsuda Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorNorifumi Fujita Dr., Norifumi Fujita Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorShigeru Sakamoto Dr., Shigeru Sakamoto Dr. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan Responsible for cold-spray-ionization mass spectrometry.Search for more papers by this authorKentaro Yamaguchi Prof. Dr., Kentaro Yamaguchi Prof. Dr. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan Responsible for cold-spray-ionization mass spectrometry.Search for more papers by this authorTakuzo Aida Prof. Dr., Takuzo Aida Prof. Dr. aida@macro.t.u-tokyo.ac.jp Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this author Kunihiko Toyofuku, Kunihiko Toyofuku Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorMd. Akhtarul Alam Dr., Md. Akhtarul Alam Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorAkihiko Tsuda Dr., Akihiko Tsuda Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorNorifumi Fujita Dr., Norifumi Fujita Dr. Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this authorShigeru Sakamoto Dr., Shigeru Sakamoto Dr. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan Responsible for cold-spray-ionization mass spectrometry.Search for more papers by this authorKentaro Yamaguchi Prof. Dr., Kentaro Yamaguchi Prof. Dr. Laboratory of Analytical Chemistry, Department of Pharmaceutical Technology, Faculty of Pharmaceutical Sciences at Kagawa Campus, Tokushima Bunri University, Shido, Sanuki-city 769-2193, Japan Responsible for cold-spray-ionization mass spectrometry.Search for more papers by this authorTakuzo Aida Prof. Dr., Takuzo Aida Prof. Dr. aida@macro.t.u-tokyo.ac.jp Department of Chemistry and Biotechnology, School of Engineering and Center for NanoBio Integration, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan, Fax: (+81) 3-5841-7310Search for more papers by this author First published: 20 August 2007 https://doi.org/10.1002/anie.200701668Citations: 60 † The present work was sponsored by a Grants in Aid for Scientific Research (No. 17350044) and Encouragement of Young Scientists (No. 18750113) from the Ministry of Education, Science, Sports, and Culture, Japan. M.A.A. thanks the JSPS Postdoctoral Fellowship for Foreign Researchers. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Majority rules: “Chiral amplification” in asymmetric transformations can be realized if a helical supramolecular polymer, derived from the substrate (S), obeys the “majority rule” in determining its handedness. This concept works properly for the asymmetric transformation of a chirality-memorizing D2-symmetric saddle-shaped porphyrin. Citing Literature Supporting Information Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2007/z701668_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume46, Issue34August 27, 2007Pages 6476-6480 RelatedInformation
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