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Unexpected chemoselectivity in the Schiff condensation of amines with η2(C,O)- η 1 (O)-coordinated aldehyde

2009; Royal Society of Chemistry; Volume: 39; Issue: 5 Linguagem: Inglês

10.1039/b921892k

1477-9234

Celedonio M. Álvarez, Raúl García‐Rodríguez, J.M. Martin-Alvarez, Daniel Miguel,

Metal complexes synthesis and properties

The aldehyde function coordinated as eta(1); eta(2) is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.