Self‐Assembly of M 24 L 48 Polyhedra Based on Empirical Prediction
2012; Wiley; Volume: 51; Issue: 13 Linguagem: Inglês
10.1002/anie.201108731
ISSN1521-3773
AutoresJens Bunzen, Junji Iwasa, Pia Bonakdarzadeh, Eri Numata, Kari Rissanen, Sota Sato, Makoto Fujita,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoCritical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M12L24 or M24L48). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M12L24/M24L48 switchover.
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