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Total Synthesis of (±) Maoecrystal V

2010; American Chemical Society; Volume: 132; Issue: 47 Linguagem: Inglês

10.1021/ja108907x

1943-2984

Jianxian Gong, Guang Lin, Wenbo Sun, Chuang‐Chuang Li, Zhen Yang,

Traditional and Medicinal Uses of Annonaceae

A concise first total synthesis of (±) maoecrystal V (1) is reported. The synthesis features a Wessely oxidative dearomatization of a phenol, an intramolecular Diels−Alder reaction, and a Rh-catalyzed O−H bond insertion as key steps.