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BIBTEX RIS

Controlled Aqueous Atom Transfer Radical Polymerization with Electrochemical Generation of the Active Catalyst

2011; Wiley; Volume: 50; Issue: 48 Linguagem: Inglês

10.1002/anie.201105317

ISSN

1521-3773

Autores

Nicola Bortolamei, Abdirisak Ahmed Isse, Andrew J. D. Magenau, Armando Gennaro, Krzysztof Matyjaszewski,

Tópico(s)

Radical Photochemical Reactions

Resumo

Enhanced control: Electrochemically mediated atom transfer radical polymerization (ATRP) allows easy modulation of the overall rate and control of polymerization through the variation of an external applied potential, Eapp (see picture). This method has been successfully applied to aqueous ATRP of oligo(ethylene glycol) methyl ether methacrylate (OEOMA475) catalyzed by Cu/tris(2-pyridylmethyl)amine.

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