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Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3‐Dihydride‐2‐iodidecyclotetraphosphane

2012; Wiley; Volume: 51; Issue: 34 Linguagem: Inglês

10.1002/anie.201203908

1521-3773

Pierluigi Barbaro, Carla Bazzicalupi, Maurizio Peruzzini, Stefano Seniori Costantini, Piero Stoppioni,

Asymmetric Hydrogenation and Catalysis

Angewandte Chemie International EditionVolume 51, Issue 34 p. 8628-8631 Communication Iodine Activation of Coordinated White Phosphorus: Formation and Transformation of 1,3-Dihydride-2-iodidecyclotetraphosphane† Dr. Pierluigi Barbaro, Dr. Pierluigi Barbaro ICCOM CNR via Madonna del Piano,10, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Carla Bazzicalupi, Dr. Carla Bazzicalupi Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Maurizio Peruzzini, Dr. Maurizio Peruzzini ICCOM CNR via Madonna del Piano,10, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Stefano Seniori Costantini, Dr. Stefano Seniori Costantini Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorProf. Dr. Piero Stoppioni, Corresponding Author Prof. Dr. Piero Stoppioni piero.stoppioni@unifi.it Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this author Dr. Pierluigi Barbaro, Dr. Pierluigi Barbaro ICCOM CNR via Madonna del Piano,10, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Carla Bazzicalupi, Dr. Carla Bazzicalupi Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Maurizio Peruzzini, Dr. Maurizio Peruzzini ICCOM CNR via Madonna del Piano,10, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorDr. Stefano Seniori Costantini, Dr. Stefano Seniori Costantini Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this authorProf. Dr. Piero Stoppioni, Corresponding Author Prof. Dr. Piero Stoppioni piero.stoppioni@unifi.it Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Dipartimento di Chimica, Università di Firenze via della Lastruccia,3, 50019 Sesto Fiorentino, Firenze (Italy)Search for more papers by this author First published: 18 July 2012 https://doi.org/10.1002/anie.201203908Citations: 31 † Thanks are expressed to COST Action CM0802 "PhoSciNet" and MIUR (Italy) through PRIN2009 for supporting this research activity. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Double stabilization: Previously unknown polyphosphorus compounds are obtained by activation of white phosphorus (P4) coordinated between two CpRu(PPh3)2 moieties with iodine, and subsequent hydrolysis. The polyphosphorus compounds (P4H2I, P4H2, P3H5; see scheme, Cp=cyclopentadienyl) are all stabilized by coordination to two ruthenium centers. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201203908_sm_miscellaneous_information.pdf173.6 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue34August 20, 2012Pages 8628-8631 RelatedInformation