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Ir‐Catalyzed Asymmetric Allylic Substitutions with (Phosphoramidite)Ir Complexes—Resting States, Synthesis, and Characterization of Catalytically Active (π‐Allyl)Ir Complexes

2009; Wiley; Volume: 15; Issue: 42 Linguagem: Inglês

10.1002/chem.200902065

1521-3765

Stephanie Spiess, Jevgenij A. Raskatov, Christian Gnamm, Kerstin Brödner, Günter Helmchen,

Asymmetric Synthesis and Catalysis

(π-Allyl)Ir complexes: A new and very simple one-pot synthesis of (π-allyl)Ir complexes derived from phosphoramidites L is presented (see scheme). Ready availability of the allyl complexes allowed resting states and other parameters of the Ir-catalyzed allylic substitution to be determined. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.