THE 1 Π u ← 1 Δ g ELECTRONIC SPECTRUM OF NCN
1967; NRC Research Press; Volume: 45; Issue: 4 Linguagem: Inglês
10.1139/p67-108
ISSN1208-6045
Autores Tópico(s)Advanced Chemical Physics Studies
ResumoThe analysis of a new electronic absorption spectrum observed during the flash photolysis of cyanogen azide, NCN 3 , in the region 3 327 Å indicates that the spectrum belongs to a 1 Π u – 1 Δ g transition of NCN. The 1 Δ g state is metastable with respect to the [Formula: see text] ground state. The bond distance in the 1 Δ g state is 1.228 5 Å. The value of the Renner splitting parameter, εω 2 , for the 1 Π u state has been determined as −84.2 cm −1 .
Referência(s)