Artigo Revisado por pares

High temperature microwave-accelerated ruthenium-catalysed domino RCM reactions

2003; Elsevier BV; Volume: 44; Issue: 14 Linguagem: Inglês

10.1016/s0040-4039(03)00452-0

ISSN

1873-3581

Autores

Jon Efskind, Kjell Undheim,

Tópico(s)

Catalytic Cross-Coupling Reactions

Resumo

The thermal instability of ruthenium(II)-catalyst systems under prolonged heating at 88°C in RCM reactions of dienyne and triyne substrates has been circumvented by a microwave temperature increase to 160°C when the reaction times were reduced to minutes.

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