Convenient Preparation of trans -Arylalkenes via Palladium(II)-Catalyzed Isomerization of cis -Arylalkenes
2002; American Chemical Society; Volume: 67; Issue: 13 Linguagem: Inglês
10.1021/jo015880u
ISSN1520-6904
AutoresJin‐Quan Yu, Matthew J. Gaunt, Jonathan B. Spencer,
Tópico(s)Oxidative Organic Chemistry Reactions
ResumoA convenient method for the isomerization of cis-arylalkenes to their trans isomers using a palladium(II) catalyst is described. The reaction conditions are mild and general across a range of arylalkenes. The synthesis of a trans-resveratrol derivative from a mixture of alkene isomers was also completed.
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