Sulfur Vulcanization of Simple Model Olefins, Part IV: Vulcanizations of 2,3-Dimethyl-2-Butene with TMTD and Activated Zinc Dithiocarbamate/Xanthate Accelerators at Different Temperatures
1995; American Chemical Society; Volume: 68; Issue: 4 Linguagem: Inglês
10.5254/1.3538757
ISSN1943-4804
AutoresP. Versloot, Jaap G. Haasnoot, J. Reedijk, Martin van Duin, Jos Put,
Tópico(s)Silicone and Siloxane Chemistry
ResumoAbstract The mechanism of the accelerated sulfur vulcanization of rubber was studied by the use of 2,3-dimethyl-2-butene (C6H12, TME) as a simple, low-molecular model alkene. Treatment of TME with a mixture of ZnO, S8 and the classical accelerator TMTD at temperatures above 100°C yields a mixture of addition products ((C6H11—Sn—C6H11) ). In the temperature range of 50 up to 100 °C only intermediate products, C6H11—Sn—S(S)CN(CH3)2 are obtained. Room temperature vulcanization is feasible using highly reactive accelerators, such as xanthate derivatives. These derivatives result in formation of the crosslink precursors which are converted to the actual crosslink in the presence of zinc dithiocarbamates. The addition of (secondary) amines enhances the solubility of the dithiocarbamates, and therefore the reactivity of the xanthate/zinc dithiocarbamate combination.
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