Enhanced ionic conductivity of Li3.5Si0.5P0.5O4 with addition of lithium borate
2015; Elsevier BV; Volume: 283; Linguagem: Inglês
10.1016/j.ssi.2015.10.009
ISSN1872-7689
AutoresDawei Wang, Guiming Zhong, Yixiao Li, Zhengliang Gong, Matthew J. McDonald, Jin‐Xiao Mi, Riqiang Fu, Zhicong Shi, Yong Yang,
Tópico(s)Thermal Expansion and Ionic Conductivity
ResumoA series of lithium borate added electrolyte compounds, xLi3BO3-(1−x)Li3.5Si0.5P0.5O4 (0 ≤ x ≤ 0.2), are synthesized and characterized. This so-called LISICON electrolyte system is analyzed by using X-ray diffraction (XRD), scanning electron microscopy (SEM), solid state nuclear magnetic resonance (ss-NMR), electrochemical impedance spectra (EIS), and direct current (DC) polarization methods. From 11B MAS NMR spectra, it is demonstrated that a small fraction of boron exists in the form of BO4, while its majority settles at grain boundaries in the form of BO3, indicating that lithium borate glasses play a role as sintering assistant. This prominently increases the relative density of samples, and is beneficial to the ionic conductivity. Further results show that the electrical conduction of lithium borate added LISICONs is dominated by Li+ ions, with a transference number of tLi+ ≥ 0.996 and a corresponding ionic conductivity of about 6.5 × 10−6 S cm−1 at room temperature, almost two times that of pristine Li3.5Si0.5P0.5O4.
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