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The Stereoisomers of Nerolidol: Separation, Analysis and Olfactoric Properties

1992; De Gruyter; Volume: 47; Issue: 3-4 Linguagem: Inglês

10.1515/znc-1992-3-422

1865-7125

Vera Schubert, Armin Dietrich, Thomas Ulrich, Armin Mosandl,

Asymmetric Synthesis and Catalysis

Abstract The sesquiterpenoic alcohol nerolidol was separated into its 4 stereoisomers by MPLC of the diastereomeric (1 S, 4 R)-camphanoates. An analytical GC method was found by which both the enantiomeric pairs of (Z)- and (E)-nerolidol are resolved on a chiral cyclodextrin stationary phase. The olfactoric properties of the nerolidol stereoisomers were investigated.