Recent Developments in Negishi Cross-Coupling Reactions
2016; American Chemical Society; Volume: 6; Issue: 3 Linguagem: Inglês
10.1021/acscatal.5b02718
ISSN2155-5435
AutoresDiana Haas, Jeffrey M. Hammann, Robert Greiner, Paul Knochel,
Tópico(s)Organoboron and organosilicon chemistry
ResumoThis Perspective describes general methods for the preparation of polyfunctional zinc organometallics and their use in Negishi cross-coupling reactions. Recent advances including new ligands and palladium catalysts are described. Related Negishi cross-coupling reactions involving Ni-, Cu-, Co-, and Fe-catalyzed cross-couplings are covered. The availability of a range of zinc organometallics combined with new efficient catalysts allows for efficient cross-coupling reactions with various organic electrophiles under usually mild conditions.
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