Effect of nano-titania (η-TiO2) content on the mechano-physical properties of a magnesia refractory composite
2016; Elsevier BV; Volume: 42; Issue: 7 Linguagem: Inglês
10.1016/j.ceramint.2016.02.064
ISSN1873-3956
AutoresEdén A. Rodríguez, Fresia Hernández Moreno, J.A. Aguilar-Martínez, A.E. Montes-Mejía, Juan Jacobo Ruíz Valdés, R. Puente-Ornelas, José Enciso Contreras,
Tópico(s)Inorganic Chemistry and Materials
ResumoThe mechano-physical properties of a sintered magnesia matrix containing 0–8 wt% nano-titania (η-TiO2) have been investigated. The crystalline phases and microstructure characteristics of the refractory specimens sintered by solid state at 1500 °C for 4 h in an electric furnace were studied by X-ray diffraction (XRD), and scanning electron microscopy (SEM) with microanalysis (EDS), respectively. The physical properties are reported in terms of density and porosity. The mechanical behavior was evaluated by a cold crushing strength (CCS) test. As a result, it was found that the presence of η-TiO2 in the magnesia matrix induced titanates formation (Mg2TiO4 and CaTiO3), which improved the sintering process. Nano-titania also produced a fine-grained microstructure with intergranular second phase particles, which remain at the boundary and exert a pinning effect. In general, the addition of 5 wt% of η-TiO2 contributed to reach a maximum increment in physical and mechanical properties.
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