Portal de Periódicos da CAPES

Mesoporous MoS 2 as a Transition Metal Dichalcogenide Exhibiting Pseudocapacitive Li and Na‐Ion Charge Storage

2016; Wiley; Volume: 6; Issue: 9 Linguagem: Inglês

10.1002/aenm.201501937

1614-6840

John B. Cook, Hyung‐Seok Kim, Yan Yan, Jesse S. Ko, Shauna Robbennolt, Bruce Dunn, Sarah H. Tolbert,

MXene and MAX Phase Materials

The ion insertion properties of MoS 2 continue to be of widespread interest for energy storage. While much of the current work on MoS 2 has been focused on the high capacity four‐electron reduction reaction, this process is prone to poor reversibility. Traditional ion intercalation reactions are highlighted and it is demonstrated that ordered mesoporous thin films of MoS 2 can be utilized as a pseudocapacitive energy storage material with a specific capacity of 173 mAh g −1 for Li‐ions and 118 mAh g −1 for Na‐ions at 1 mV s −1 . Utilizing synchrotron grazing incidence X‐ray diffraction techniques, fast electrochemical kinetics are correlated with the ordered porous structure and with an iso‐oriented crystal structure. When Li‐ions are utilized, the material can be charged and discharged in 20 seconds while still achieving a specific capacity of 140 mAh g −1 . Moreover, the nanoscale architecture of mesoporous MoS 2 retains this level of lithium capacity for 10 000 cycles. A detailed electrochemical kinetic analysis indicates that energy storage for both ions in MoS 2 is due to a pseudocapacitive mechanism.