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Assorted Phenoxyl-Radical Polymers and Their Application in Lithium-Organic Batteries

2016; Wiley; Volume: 37; Issue: 8 Linguagem: Inglês

10.1002/marc.201500702

1521-3927

Thomas Jähnert, Martin D. Hager, Ulrich S. Schubert,

Polyoxometalates: Synthesis and Applications

Macromolecular Rapid CommunicationsVolume 37, Issue 8 p. 725-730 Communication Assorted Phenoxyl-Radical Polymers and Their Application in Lithium-Organic Batteries Thomas Jähnert, Thomas Jähnert Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanySearch for more papers by this authorMartin D. Hager, Martin D. Hager Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanySearch for more papers by this authorUlrich S. Schubert, Corresponding Author Ulrich S. Schubert Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanyE-mail: ulrich.schubert@uni-jena.deSearch for more papers by this author Thomas Jähnert, Thomas Jähnert Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanySearch for more papers by this authorMartin D. Hager, Martin D. Hager Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanySearch for more papers by this authorUlrich S. Schubert, Corresponding Author Ulrich S. Schubert Laboratory of Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstr. 10, 07743 Jena, Germany Center for Energy and Environmental Chemistry Jena (CEEC Jena), Friedrich Schiller, University Jena, Philosophenweg 7a, 07743 Jena, GermanyE-mail: ulrich.schubert@uni-jena.deSearch for more papers by this author First published: 03 March 2016 https://doi.org/10.1002/marc.201500702Citations: 18Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract The synthesis and electrochemical characterization of novel polymers bearing phenoxyl-radicals as redox-active side chains is described. The monomers are synthesized from the corresponding phenols and quinones, respectively. These compounds are subsequently poly­merized via ring-opening metathesis polymerization. The electrochemical properties of the phenoxyl-radical polymers are characterized using cyclic voltammetry and the most promising polymer is investigated as active material in a lithium coin-cell, creating the first phenoxyl-lithium battery. These phenoxyl-containing polymers represent interesting anode materials for organic radical and lithium batteries due to their suitable redox-potentials and possibility to create batteries with higher potentials as well as straightforward synthesis procedures. Citing Literature Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description marc201500702-sup-0001-S1.pdf428.3 KB Supplementary Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume37, Issue8April 2016Pages 725-730 RelatedInformation