Economical and green biodiesel production process using river snail shells-derived heterogeneous catalyst and co-solvent method
2016; Elsevier BV; Volume: 209; Linguagem: Inglês
10.1016/j.biortech.2016.03.038
ISSN1873-2976
AutoresWuttichai Roschat, Theeranun Siritanon, Teadkait Kaewpuang, Boonyawan Yoosuk, Vinich Promarak,
Tópico(s)Lubricants and Their Additives
ResumoRiver snail shells-derived CaO was used as a heterogeneous catalyst to synthesize biodiesel via transesterification of palm oil with methanol. The shell materials were calcined in air at 600–1000 °C for 3 h. Physicochemical properties of the resulting catalysts were characterized by TGA–DTG, XRD, SEM, BET, XRF, FT-IR and TPD. CaO catalyzed transesterification mechanism of palm oil into biodiesel was verified. The effects of adding a co-solvent on kinetic of the reaction and %FAME yield were investigated. %FAME yield of 98.5% ± 1.5 was achieved under the optimal conditions of catalyst/oil ratio of 5 wt.%; methanol/oil molar ratio of 12:1; reaction temperature of 65 °C; 10% v/v of THF in methanol and reaction time of 90 min. The results ascertained that river snail shells is a novel raw material for preparation of CaO catalyst and the co-solvent method successfully decreases the reaction time and biodiesel production cost.
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