Flash Spark Plasma Sintering (FSPS) of α and β SiC
2016; Wiley; Volume: 99; Issue: 5 Linguagem: Inglês
10.1111/jace.14158
ISSN1551-2916
AutoresSalvatore Grasso, Theo Saunders, Harshit Porwal, Ben Milsom, Adam Tudball, Mike Reece,
Tópico(s)Aluminum Alloys Composites Properties
ResumoA novel processing methodology that allows combined preheating and Flash‐ SPS ( FSPS ) of silicon carbide‐based materials has been developed. Beta‐SiC (+10 wt% B 4 C) powders were densified (Ф 20 mm) up to 96% of their theoretical density in 17 s under an applied pressure of 16 MP a (5 kN ). The flash event was attributed to the sharp positive temperature dependence of the electrical conductivity (thermal runaway) of SiC, and a sudden increase in electric power absorption (Joule heating) of the samples after a sufficient preheating temperature (>600°C) was reached. The microstructural evolution was analyzed by examining materials densified by FSPS in the range of 82%–96% theoretical densities. FEM modeling results suggest that the FSPS heating rate was of the order of 8800°C/min. A comparative analysis was done between FSPS and reference samples (sintered using conventional SPS in the temperature range of 1800°C–2300°C). This allowed for a better understanding of the temperatures generated during FSPS , and in turn the sintering mechanisms. We also demonstrated the scalability of the FSPS process by consolidating a large α‐SiC disk (Ф 60 mm) in about 60 s inside a hybrid SPS furnace equipped with an induction heater, which allowed us to achieve sufficient preheating (1600°C) of the material to achieve FSPS .
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