Triple Bonding to Germanium: Characterization of the Transition Metal Germylynes (η 5 -C 5 H 5 )(CO) 2 M⋮Ge-C 6 H 3 -2,6-Mes 2 (M = Mo, W; Mes = −C 6 H 2 -2,4,6-Me 3 ) and (η 5 -C 5 H 5 )(CO) 2 M⋮Ge-C 6 H 3 -2,6-Trip 2 (M = Cr, Mo, W; Trip = −C 6 H 2 -2,4,6-i-Pr 3 ) and the Related Single Bonded Metallogermylenes (η<…
2000; American Chemical Society; Volume: 122; Issue: 4 Linguagem: Inglês
10.1021/ja992937+
ISSN1943-2984
AutoresLihung Pu, Brendan Twamley, Scott T. Haubrich, Marilyn M. Olmstead, B.V. Mork, Richard S. Simons, Philip P. Power,
Tópico(s)Synthesis and Properties of Aromatic Compounds
ResumoThe synthesis and characterization of several m-terphenyl stabilized germylyne transition metal complexes and related metallogermylenes are reported. The reaction of Na[M(η5-C5H5)(CO)3] (M = Cr, or...
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