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Flexible Polyimide Films Hybrid with Functionalized Boron Nitride and Graphene Oxide Simultaneously To Improve Thermal Conduction and Dimensional Stability

2014; American Chemical Society; Volume: 6; Issue: 11 Linguagem: Inglês

10.1021/am501323m

1944-8252

Mei‐Hui Tsai, I‐Hsiang Tseng, Jen‐Chi Chiang, Jheng‐Jia Li,

Synthesis and properties of polymers

Coupling agent-functionalized boron nitride (f-BN) and glycidyl methacrylate-grafted graphene (g-TrG) are simultaneously blended with polyimide (PI) to fabricate a flexible, electrically insulating and thermally conductive PI composite film. The silk-like g-TrG successfully fills in the gap between PI and f-BN to complete the thermal conduction network. In addition, the strong interaction between surface functional groups on f-BN and g-TrG contributes to the effective phonon transfer in the PI matrix. The thermal conductivity (TC) of the PI/f-BN composite films containing additional 1 wt % of g-TrG is at least doubled to the value of PI/f-BN and as high as 16 times to that of the pure PI. The hybrid film PI/f-BN-50/g-TrG-1 exhibits excellent flexibility, sufficient insulating property, the highest TC of 2.11 W/mK, and ultralow coefficient of thermal expansion of 11 ppm/K, which are perfect conditions for future flexible substrate materials requiring efficient heat dissipation.