Evaluation of Triflate Displacement by Water in CH 2 Cl 2 Solution: Comparison of trans -[Rh(CO)(PPh 3 ) 2 (OSO 2 CF 3 )] and the Crystalline Salt trans -[Rh(CO)(PPh 3 ) 2 (OH 2 )][OTf]
1996; American Chemical Society; Volume: 35; Issue: 10 Linguagem: Inglês
10.1021/ic951287h
ISSN1520-510X
AutoresAnna Svetlanova-Larsen, John L. Hubbard,
Tópico(s)Inorganic and Organometallic Chemistry
ResumoAlthough trans-[Rh(CO)(PPh3)2(OH2)][OSO2CF3] crystallizes from H2O-saturated CH2Cl2, trans-[Rh(CO)(PPh3)2(OSO2CF3)] is the only detectable complex in solution. The OSO2CF3- ligand is shown to be a stronger ligand than H2O and BF4- in CH2Cl2.
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