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Artigo Revisado por pares
BIBTEX RIS

Wide Control of Proton Conductivity in Porous Coordination Polymers

2011; American Chemical Society; Volume: 133; Issue: 7 Linguagem: Inglês

10.1021/ja109810w

ISSN

1943-2984

Autores

Akihito Shigematsu, Teppei Yamada, Hiroshi Kitagawa,

Tópico(s)

Fuel Cells and Related Materials

Resumo

The proton conductivities of the porous coordination polymers M(OH)(bdc-R) [H(2)bdc = 1,4-benzenedicarboxylic acid; M = Al, Fe; R = H, NH(2), OH, (COOH)(2)] were investigated under humid conditions. Good correlations among pK(a), proton conductivity, and activation energy were observed. Fe(OH)(bdc-(COOH)(2)), having carboxy group and the lowest pK(a), showed the highest proton conductivity and the lowest activation energy in this system. This is the first example in which proton conductivity has been widely controlled by substitution of ligand functional groups in an isostructural series.

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