Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols
2011; American Chemical Society; Volume: 30; Issue: 13 Linguagem: Inglês
10.1021/om200437n
ISSN1520-6041
AutoresMarcello Bertoli, A. Choualeb, Alan J. Lough, Brandon d. Moore, Denis M. Spasyuk, Dmitry G. Gusev,
Tópico(s)Catalysis for Biomass Conversion
ResumoA series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C2H4PiPr2)2] and OsH2(CO)[HN(C2H4PiPr2)2] possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.
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