Encapsulation of Phthalocyanine Supramolecular Stacks into Virus-like Particles
2011; American Chemical Society; Volume: 133; Issue: 18 Linguagem: Inglês
10.1021/ja110752u
ISSN1943-2984
AutoresMelanie Brasch, Andrés de la Escosura, Yujie Ma, Charlotte Uetrecht, Albert J. R. Heck, Tomás Torres⊗, Jeroen J. L. M. Cornelissen,
Tópico(s)Luminescence and Fluorescent Materials
ResumoWe report herein the encapsulation of a water-soluble phthalocyanine (Pc) into virus-like particles (VLPs) of two different sizes, depending on the conditions. At neutral pH, the cooperative encapsulation/templated assembly of the particles induces the formation of Pc stacks instead of Pc dimers, due to an increased confinement concentration. The Pc-containing VLPs may potentially be used as photosensitizer/vehicle systems for biomedical applications such as photodynamic therapy.
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