REACTIONS OF HYDRAZIDOYL HALIDES: SYNTHESIS OF IMIDAZO[2,1-B]THIAZOLE, THIAZOLO[2,3-C]-AS-TRIAZOLE AND HETEROCYCLIC ENAMINONITRILES

1988; Taylor & Francis; Volume: 36; Issue: 1-2 Linguagem: Inglês

10.1080/03086648808079007

ISSN

0308-664X

Autores

Abdou O. Abdelhamid, Mamdouh A. M. Afifi,

Tópico(s)

Synthesis and biological activity

Resumo

Abstract Arylazo derivatives of imidazo[2,1-b]thiazoles could be obtained via reaction of hydrazidoyl halides with 2-aminothiazole. Thiazolo[2,3-c]-as-triazole and heterocyclic enaminonitriles were obtained in good yields from hydrazidoyl halides and triethylamine and from malonitrile, respectively. Pyrazolo[3,4-d]pyrimidines and pyrazolo[3,4-d]pyridazines were obtained via reaction of heterocyclic enaminonitriles with formic acid and hydrazine hydrate, respectively. The structures of the products were assigned and confirmed on the basis of their elemental analyses and spectral data.

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