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Artigo Revisado por pares
BIBTEX RIS

Oxidant-Free Conversion of Primary Amines to Nitriles

2013; American Chemical Society; Volume: 135; Issue: 44 Linguagem: Inglês

10.1021/ja409223a

ISSN

1943-2984

Autores

Kuei-Nin T. Tseng, Andrew Rizzi, Nathaniel K. Szymczak,

Tópico(s)

Nanomaterials for catalytic reactions

Resumo

An amide-derived NNN-Ru(II) hydride complex catalyzes oxidant-free, acceptorless, and chemoselective dehydrogenation of primary and secondary amines to the corresponding nitriles and imines with liberation of dihydrogen. The catalyst system tolerates oxidizable functionality and is selective for the dehydrogenation of primary amines (-CH2NH2) in the presence of amines without α-CH hydrogens.

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